WebMay 1, 2013 · A very simple, green and efficient protocol is developed in which zinc chloride-exchanged K10-montmorillonite (clayzic) is employed as a Lewis acid catalyst in aqueous media at room temperature ... WebClayzic is a good example of an environmentally friendly catalyst with particular value as an alternative to the hazardous reagent aluminium chloride in Friedel-Crafts reactions. The structure and properties of this catalyst are, however, poorly understood. X-Ray diffraction studies show that thermal treatment of either clayzic or its base ...
ENVIRONMENTALLY FRIENDLY CHEMISTRY USING SUPPORTED …
WebJun 11, 2024 · However, the clayzic catalyst is less selective (≈80% selectivity for diphenylmethane) [12] and moreover it is highly hygroscopic in nature, it rapidly loses its activity when exposed to air [13] . The above results of the ZnCl 2 /Mont.-K10 are consistent with this. The high hygroscopic nature of clayzic catalyst puts a severe restriction on ... WebJan 5, 2011 · A very simple, green and efficient protocol is developed in which zinc chloride-exchanged K10-montmorillonite (clayzic) is employed as a Lewis acid catalyst in aqueous media at room temperature for the synthesis of various benzimidazoles and quinoxalines from carbonyl compounds and o-phenylenediamine.Among the various catalysts … ftb forfeited ca meaning
Zn²⁺-K10-clay (clayzic) as an efficient water-tolerant, solid …
WebZinc was bound on montmorillonite K10 by cation exchange to obtain a catalyst named clayzic. In the Friedel-Crafts benzylation of 1,4-dimethoxybenzene, this catalyst was used for the synthesis of … Expand. 2. View 1 excerpt, cites methods; Save. Alert. WebDownload scientific diagram Variation of the TOR with the e ective ÿOÿZnÿCl concentration per unit area of clayzic catalyst. from publication: Thermal Activation of a Clayzic … WebJun 11, 1993 · Besides such enzyme-like aspects, "clayzic" as a catalyst presents the advantage of lesser (by up to three orders of magnitude) amounts than demanded of the standard Lewis acids used in Friedel-Crafts processesl. This has been put to industrial and commercial use 14. Returning to competitive inhibition, observed when alkylating toluene … gigabyte z170 gaming 5 boot with no network